Finding which materials apply to a selected face

If I am in edit mode and select a face, is there any way for me to identify which materials (if any) are associated with that face? I have imported a model which has resulted in the creation of many materials with intriguing names and I am trying to figure out which ones apply to which faces. I know I can Select all faces of a given material but is it possible to go the other way?

Select the face and the material it uses will be the one selected in the materialsettings