Install the package for the python version used in blender (3.2). Then copy the package from e.g. C:\Python32\Lib\site-packages to
C:\Program Files\Blender Foundation\Blender\2.64\scripts\modules. (You may need to install python 3.2 first)
OR
Get the package compiled for your system from somewhere and copy it to …\scripts\modules
Now you can import nltk in every script.
Apparently too many people complained so numpy doesn’t get bundled by default, you have to install it however you install other python modules and/or mess with sys.path to get python to see it.
Just do it exactly the same way you did with nltk.
At http://www.lfd.uci.edu/~gohlke/pythonlibs/ you can find numpy builds for python 3.2.
For e.g. Win7,64bit choose numpy-unoptimized-1.6.2.win-amd64-py3.2.*exe