If you are talking about proportional editing, it can be used if the non-linear scaling is non-linear in one of these ways:
It is intended precisely for that - any proportional non-linear transforms.
Just to be clear: using a lattice like Joseph suggests would be a lot more flexible and probably easier to use and I see no reason to use proportional editing instead, but you could if you wanted for some reason and the falloff modes matched what you need. I mean if we are talking about the options…