How does one access RGB/HSV values in the Texture Paint color picker?
Click on the colour swatch in any of Blender’s colour pickers
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@JohnMalcolm1970 is 100% correct, but just in case you need a larger view to get some context:
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That’s what I get for clicking on the color wheel.
Swatch. Not the wheel. Swatch. Not the wheel. Swatch. Not the wheel. Swatch. Not the wheel. Swatch. Not the wheel. Swatch. Not the wheel. Swatch. Not the wheel. Swatch. Not the wheel. Swatch. Not the wheel. Swatch. Not the wheel…
Personally, I think it should display RGB/HSV values as you drag over the color wheel.
Assuming you’re in texture paint mode, right click to get this menu, then click the top left square to get HSV and HEX color controls.